ALFALFA



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ALFALFA
Alfalfa; German: Blaue Luzerne, English: Alfalfa, Lucerne.

Aerial parts.

Trilobuladas toothed leaves and flowers in blue violet grouped in clusters, coiled in the form of pods helix, which contains seeds and bright knots and with woody roots. Alfalfa a typical example of the genera of the subfamily of Lotoideas (Faboideas)

Source.

Alfalfa (not to be confused with Stipa tenacissima L. Poacea) is a tetraploid natural, spontaneous in Europe (south of latitude 42) You can easily hybridizing with other species of the genus, for example, with M. falcata (M. x half Pers)

Chemical composition.

The study of Genina has shown that it is derived from neutral oleaneno (soyasapo - genoles) or acid (acid medicagénico, hederagenina, acid oleanólico) The heterósidos found in all organs, as well as upcoming species such as M. media [5] The use of structural complexes, has enabled heterósidos show that the roots of the variety "Lutetia" are in heterósidos 3 esters osídicos in 28 acid medicagénico and the hederagenina. They can carry six molecules dare [6] The aerial parts of the North American varieties have similar structures containing, on its part osídica, an acid urónico: soyasaponina I azuquisaponinas [7]

They know other components whose presence is important: protein (20%) canavanine, and naphthoquinone benzo (for example, vitamin K) polyols, glycero - glucolípidos, cumarinas (cumestrol) quaternary amino acids) Leaves infested with fungus produced numerous cumestanos. It has also revealed the presence of isoflavones and acidic phenols, as well as many minerals: calcium, phosphorus, iron, zinc, copper, selenium, silica.

Pharmacological data.

Administered in large doses to ruminants, the saponosides of alfalfa are revealed toxic. In the cold - blooded animals, are fungistáticos, some are blood and seem to interfere with the activity of certain enzymes. Its properties have been linked to estrogenic isoflavones. The cumestrol, coumarin of the road whose molecular structuresare related to those of estradiol, also has estrogenic properties. The addition of alfalfa rabbit's diet to prevent high blood cholesterol and atherosclerosis. The same is true in monkeys, which have carefully studied the effects of saponosides the absorption and excretion of cholesterol, lipidemia and excretion of bile acids.

A study conducted over a long period of time in rabbits subjected to a regime rich in cholesterol, shows that the seeds of alfalfa and saponosides decrease cholesterol. In the mouse, there is an increase in cholesterol and fat fecal. These effects are due to the ownership of many saponosides to form insoluble combinations with cholesterol (also used as a method of isolating these molecules) tested in vitro, rat. It has not yet been proven to work in humans.

Employment.

Drug use is restricted, at least in Western Europe. Although some animal species have been observed effects on growth, sensitivity varies between them. A rat study, tends to prove the absence of toxicity of saponosides administered over a long period of time. The richness of the plant in vitamins and calcium, as well as the presence of phytoestrogens ago that the carrier is used in the treatment of osteoporosis.

The drug.

The stems of alfalfa are angular and Ramos. The leaflets, alternate and nearly linear, toothed are at the top and end up in a small tip. Presents stipules oval - lanceolate, toothed at its base and acuminate. The heads grouped five to forty feet short of flowers. The fruit is a pod on a variable: straight, arched, spiraling from 1 to 3 laps, never thorny. Have developed different spectrophotometric or chromatographic techniques (including gas chromatography and thin layer chromatography) to perform the evaluation of saponosides present in the drug.

Bibliography.

Y. BIRK and I. PERI.

Saponins. In: Toxic constitute of plant foodstuff, i. e. Lien, ed. New York, Academic Press, p. 161 - 182, 1980.

I. Kitagawa, M. Yoshikawa, H. K. WANG, M. SAITO, V TOSIRISUK, T. Fujiwara and K. I. Tomita.

Revised structures of soyasapogenols A, B and E, oleanene - sapogenols from soybean. Structure of soyasaponins I, II and III.

Chem. Phar. Bull. 30, 2294 - 2297, 1982; see also I. Kitagawa et al. Ibid. 36, 153 - 161, 1988.

S. SHANY, B. Gestetner, Y. BIRK, A. BONDI and I. KIRSON.

Isolation of hederagenin and its saponin from alfalfa (Medicago sativa) Isr. J. Chem. 10, 881 - 884, 1972; see also B. Gestetner, Phytochemistry, 10, 2221 2223, 1971.

L. G. WEST.

Identification of oleanolic acid from sapogenins present in lucerne (alfalfa) root.

J. Sci. Food Agric. 30, 540 - 542, 1979.

W. OLESZEK and M. JURZYSTA.

Isolation, chemical characterization and biological activity of alfalfa (Medicago half Pers. Root saponins.

Acta Soc. Bot. Pol. 55, 22 - 23, 1986.

G. MASSIOT, C. LAVAUD, L. LE MEN - OLIVIER, G. VAN BINST, S. P. F. MILLER and H. M. FALES.

Structural elucidation of alfalfa root saponins by mass spectrometry and nuclear magnetic renonance analysis.

J. Chem. Soc. Beijing I, 3071 - 3079, 1988.

I. Kitagawa, T. TANIYAMA, T. MURAKAMI, M. YOSHIHARA and M. Yoshikawa.

Saponin and sapogenol. XLVI. On the part of constituents in aereal american alfalfa, Medicago sativa L.

The Structure of dehidrosoyasoponin I.

Yakygaku Zasshi, 108, 547 - 554, 1988.

R. W. MILLER, G. F. SPENCER and A. R. SPENCER.

5 ' - Methoxisativan, a new isoflavan from alfalfa.

J. Nat. Prod. 52, 634 - 636, 1989; see also P. M. DEWICK, Isoflavonoids, in: The flavonoids: advances in research, JB Harborne and T. J. Mabry, eds. London, Chapman and Hall, P. 535 - 640, 1982.

R. MALINOW, W. E. CONNOR, P. McLaughlin, C. STAFFORD, D. S. LIN, A. L. LIVINGSTON, G. O. KOHLER and W. P. McNULTY.

Cholesterol and bile acid balance in Maraca fascicularis. Effects of alfalfa saponins.

M. R. MALINOW, P. McLaughlin, C. STAFFORD, A. L. LIVINGSTON and G. O. KOHLER.

Alfalfa saponins and alfalfa seeds. Dietary effects in cholesterol - fed rabbits.

Atherosclerosis 37. 433 - 438, 1980.

J. A. STORY, S. L. LEPAGE, M. S. PETRO, L. G. WEST, M. M. CASSIDY, F. G. Lightfoot and G. V. VAHOUNY.

Interactions of Alfalfa plant and sprout saponins with choleterol in vitro and in cholesterol - fed rat.

Am. J. Clin. Nutr. 39, 917 - 929, 1984.

M. R. MALINOW, W. P. McNULTY, P. McLaughlin, C. STAFFORD, A. K. BURNS, A. L. LIVINGSTON and G. O. KOHLER.

The toxicity of alfalfa saponins in rats.

Fd. Cosmet. Toxicol. 19, 443 - 445, 1981.

M. MOHSIN and A. K. PAL.

Indian J. Exp. Biol. 7, 15 - 76, 1977.

D. RAO and G. BORIE.

Simple gas chromatographic method for the determination of medicagenic acid in alfalfa (Medicago sativa)

J. Chromatogr. 410) 169 - 175, 1987; see also:

W. OLESZEK, Solid - phase extraction - fractionation of alfalfa saponins, J. Sci. Food Agric. 44, 43 - 49, 1988.

Diseases whose treatment is appropriate in this plant.

Nervous spasm.

Menopause.

Osteoarthritis.

Osteoporosis.


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